Article Sidebar

Download
PDF
Statistic
Read Counter : 68 Download : 46

Downloads

Download data is not yet available.

Main Article Content

Abstract

A laboratory experiment was conducted to study zinc adsorption at eight concentrations (0, 25, 50, 100, 150, 200, 250 and 300 mg L-1) by using ZnSO4.7H2O. with two replicates were used for each concentration, where 20 mL of zinc solution was added to 1 gram of natural zeolite, synthetic zeolite, soil 1, and soil 2. Langmuir equation was used to describe the relationship between zinc adsorption and its concentration. Additionally, the Freundlich equation was used to describe adsorption of ions. Freundlich equation was found to be more important than Langmuir equation, as the values of k and b in Freundlich equation and the R2 values for natural and synthetic zeolites were higher in both soils. The second experiment involved kinetics. Zeolite and soil were kept moist at field capacity throughout the incubation period. Zinc was extracted using DTPA after each incubation period, with two replicates to study the rate of zinc release from zeolite and soil over time and its concentration in the solution. results showed a decrease in the availability of added zinc with increasing incubation time. The highest concentration of available zinc was found when zinc was added to synthetic zeolite, reaching 346 µg Zn+2 ml-1 at the end of the incubation period. The second-order equation was the most effective in describing the behavior of zinc and its reaction rate during the incubation period, representing the period of crop growth.

Keywords

Adsorption Calcareous soil Zeolite Zinc

Article Details

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

How to Cite
Al-Mashhdany, M. A. R. ., & Al-Hadethi, A. A. H. . (2023). Adsorption Reaction and Kinetics of Zn on Zeolite Mineral Comparing with Two Calcareous Soils. Basrah Journal of Agricultural Sciences, 36(2), 199–214. https://doi.org/10.37077/25200860.2023.36.2.15
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX

References

  1. Abadzic, S. D., & Ryan, J. N. (2001). Particle release and permeability reduction in a natural zeolite (clinoptilolite) and sand porous medium. Environmental Science & Technology, 35(22), 4502-4508.
  2. https://doi.org/10.1021/es001868s
  3. Al‐Mamoori, A., Krishnamurthy, A., Rownaghi, A. A., & Rezaei, F. (2017). Carbon capture and utilization update. Energy Technology, 5(6), 834-849.‏
  4. https://doi.org/10.1002/ente.201600747
  5. Alvarez-Ayuso, E., Garcia-Sanchez, A., & Querol, X. (2003). Purification of metal electroplating waste waters using zeolites. Water Research, 37, 4855-4862.
  6. https://www.sciencedirect.com/science/article/pii/S0043135403004676
  7. Arias, M., Perez–Novo, C., Osorio, F., & Lopez, E. (2005). Adsorption and desorption of copper and zinc in the surface layer of acid soil. Journal of Colloid and Interface Science, 288, 21-29.
  8. https://www.sciencedirect.com/science/article/pii/S0021979705001980
  9. Behroozi, A., Arora, M., Fletcher, T. D., & Western, A. W. (2020). Sorption and transport behavior of zinc in the soil; Implications for stormwater management. Geoderma, 367, 114243.‏
  10. https://www.sciencedirect.com/science/article/abs/pii/S0016706119318889
  11. Breck, D. W. (1973). Zeolite Molecular Sieves: Structure, Chemistry, and Use. John Wiley & Sons, Inc. 771pp.
  12. Campillo-Cora, C., Conde-Cid, M., Arias-Estévez, M., Fernández-Calviño, D., & Alonso-Vega, F. (2020). Specific adsorption of heavy metals in soils: individual and competitive experiments. Agronomy, 10(8), 1113.‏
  13. https://doi.org/10.3390/agronomy10081113
  14. Cincotti, A., Mameli, A., Locci, M. A., Orru, R., & Cao, G. (2006). Heavy metal uptake by Sardinian natural zeolites: experiment and modelling. Industrial and Engineering Chemistry Research, 45, 1074-1084.
  15. https://pubs.acs.org/doi/10.1021/ie050375z
  16. Dandanmozd, F., & Hosseinpur, A. R. (2010). Thermodynamic parameters of zinc sorption in some calcareous soils. Journal of American Science, 6(7), 298-304.‏
  17. Du, Q., Liu, S., Cao, Z., & Wang, Y. (2005). Ammonia removal from aqueous solution using natural Chinese clinoptilolite. Separation and Purification Technology, 44(3), 229-234.
  18. https://www.sciencedirect.com/science/article/pii/S1383586605000493
  19. Du, W., Yang, J., Peng, Q., Liang, X., & Mao, H. (2019). Comparison study of Zinc nanoparticles and Zinc sulphate on wheat growth: From toxicity and zinc biofortification. Chemosphere, 227, 109-116.
  20. https://pubmed.ncbi.nlm.nih.gov/30986592/
  21. Falatah, A. M., Sheta, A. S., Sallam, A. Sh., & Al-Sewailem, M. (2005). Characteristics of K+ and NH4+ adsorption and desorption by natural bentonite and zeolite minerals. Journal of Agricultural Sciences, Mansoura University, 30(3), 1739-1754.
  22. https://journals.ekb.eg/article_226354_0.html
  23. Gunay, A., Arslankaya, E., & Tosun, I. (2007). Lead removal from aqueous solution by natural and pretreated clinoptilolite: Adsorption equilibrium and kinetics. Journal of Hazardous Materials, 146, 362-371.
  24. https://www.sciencedirect.com/science/article/pii/S0304389406014890
  25. Hamidpour, M., Karamooz, M., Akhgar, A., Tajabadipour, A., & Furrer, G. (2019). Adsorption of Cd and Zn on to micaceous minerals -Effect of siderophore desferrioxamine B. Pedosphere, 29(5), 590-597.
  26. https://www.sciencedirect.com/science/article/abs/pii/S1002016017603849
  27. https://link.springer.com/article/10.1007/s11270-017-3649-1
  28. Kausar, A., Iqbal, M., Javed, A., Aftab, K., Nazli, Z.-H., Bhatti, H. N., & Nouren, S. (2018). Dyes adsorption using clay and modified clay: A review. Journal of Molecular Liquids, 256, 395-407.
  29. https://www.sciencedirect.com/science/article/pii/S0167732217346366
  30. LeVan, M. D. (Ed.). (2012). Fundamentals of adsorption: proceedings of the Fifth International Conference on Fundamentals of Adsorption, Vol. 356. Springer Science & Business Media.‏
  31. https://www.sciencedirect.com/science/article/abs/pii/B9780128188057000011
  32. Lindsay, W. L., & Norvell, W. A. (1978). Development of a DTPA soil test for Zinc, Iron, Manganese, and Copper. Soil Science Society of America Journal, 42, 421-428.
  33. https://doi.org/10.2136/sssaj1978.03615995004200030009x
  34. Mam-Rasul, G. A. (2020). Potassium adsorption in calcareous soils of Kurdistan region of Iraq. Iraqi Journal of Agricultural Sciences, 51(Special), 42-52.
  35. https://doi.org/10.36103/ijas.v51iSpecial.881
  36. Meng, Q., Chen, H., Lin, J., Lin, Z., & Sun, J. (2016). Zeolite A synthesized from alkaline assisted pre-activated halloysite for efficient heavy metal removal in polluted river water and industrial wastewater. Journal of Environmental Sciences, 50, 86-94.
  37. https://www.sciencedirect.com/science/article/pii/S1001074216310075
  38. Mhamdi, M., Elaloui, E., & Trabelsi-Ayadi, M. (2013). Adsorption of zinc by a Tunisian Smectite through a filtration membrane. Industrial Crops and Products, 47, 204-211.
  39. https://doi.org/10.1016/j.indcrop.2013.03.003
  40. Mukkanti, K., Pandeya, K. B., & Singh, R. P. (1985). Synthesis and Characterization of cobalt (III) complexes with thiophene-2-carboxylaldehyde thiosemicarbazone. Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 15(5), 613-625.‏
  41. https://www.tandfonline.com/doi/abs/10.1080/00945718508061427
  42. Nakhli, S. A. A., Delkash, M., Bakhshayesh, B. E., & Kszemian, H. (2017). Application of zeolites for sustainable agriculture: A review on water and nutrient retention. Journal of Water, Air, and Soil Pollution, 228(12), 464-498.
  43. https://doi.org/10.1007/s11270-017-3649-1
  44. Norde, W. (1986). Adsorption of proteins from solution at the solid-liquid interface. Advances in Colloid and Interface Science, 25, 267-340.
  45. https://doi.org/10.1016/0001-8686(86)80012-4
  46. Pérez-Botella, E., Valencia, S., & Rey, F. (2022). Zeolites in adsorption processes: State of the art and future prospects. Chemical Reviews, 122(24), 17647-17695.
  47. https://pubs.acs.org/doi/10.1021/acs.chemrev.2c00140
  48. Petrovic, B., Gorbounov, M., & Soltani, S. M. (2021). Influence of surface modification on selective CO2 adsorption: A technical review on mechanisms and methods. Microporous and mesoporous materials, 312, 110751.
  49. https://doi.org/10.1016/j.micromeso.2020.110751
  50. Rassaei, F., Hoodaji, M., & Abtahi, S. A. (2020). Cadmium speciation as influenced by soil water content and zinc and the studies of kinetic modeling in two soils textural classes. International Soil and Water Conservation Research, 8(3), 286-294.
  51. https://doi.org/10.1016/j.iswcr.2020.05.003
  52. Sposito, G. (1984). The surface chemistry of soils. Oxford University Press. 234pp.
  53. Suleiman, A. M. (2016). Removal of zinc ions from aqueous solutions using natural Syrian zeolite. Tishreen University Journal for Research and Scientific Studies, 38(3), 63-79. (In Arabic).
  54. Taalab, A. S., Ageeb, G. W., Siam, H. S., & Mahmoud, S. A. (2019). Some Characteristics of Calcareous soils. A review. Middle East Journal of Agriculture Research, 8(1), 96-105.
  55. ‏
  56. Thajeel, A. S. (2013). Isotherm, kinetic and thermodynamic of adsorption of heavy metal ions onto local activated carbon. Aquatic Science and Technology, 1(2), 53-77.
  57. https://doi.org/10.5296/ast.v1i2.3763
  58. Xing, W., Zhou, F., Zhu, R., Wang, X., & Chen, T. (2023). Performance and mechanism of Zn-contaminated soil through microbe-induced calcium carbonate precipitation. Buildings, 13(8), 1974. ‏
  59. https://doi.org/10.3390/buildings13081974
  60. Yuvaraj, M., & Subramanian, K. S. (2018). Development of slow-release Zn fertilizer using nano-zeolite as a carrier. Journal of Plant Nutrition, 41(3), 311-320.
  61. https://www.tandfonline.com/doi/full/10.1080/01904167.2017.1381729
  62. Zanin, E., Scapinello, J., de Oliveira, M., Rambo, C. L., Franscescon, F., Freitas, L., de Mello, J.M.M., Fiori, M.A., Oliveira, J. V., & Dal Magro, J. (2017). Adsorption of heavy metals from wastewater graphic industry using clinoptilolite zeolite as adsorbent. Process Safety and Environmental Protection, 105, 194-200.
  63. ‏https://doi.org/10.1016/j.psep.2016.11.008
  64. Zarga, Y., Boubaker, H. B., Ghaffour, N., & Elfil, H. (2013). Study of calcium carbonate and sulfate co-precipitation. Chemical Engineering Science, 96, 33-41.‏